Mechanical Performance Enhancement of EPDM Rubber Nanocomposites Reinforced with Graphene, Carbon Nanotubes, and Silica for Industrial Diaphragm Applications

Authors

  • Al-Hadrayi Ziadoon M. R. Mechanical Engineering Department, Faculty of Engineering, University of Kufa, Najaf, Iraq
  • Hayder H. Khaleel Engineering Technical College, Najaf, Al-Furat Al-Awsat Technical University, Al-Najaf 31001, Iraq
  • Ammar R. Hasan Materials Engineering Department, Faculty of Engineering, University of Kufa, Najaf, Iraq
  • Emad Kadum Njim Department of Mechanical Power Engineering, College of Technical Engineering, University of Al Maarif, Al Anbar, Iraq

DOI:

https://doi.org/10.5281/zenodo.21910721

Keywords:

Rubber Composites, EPDM, Experimental Tests, Nanoparticles, Mechanical Properties

Abstract

Ethylene propylene diene monomer, or EPDM, is a rubber used in several industrial applications. In pipes for sealing water or for rotating equipment, the same can be said of thermal and electrical insulation. EPDM is not only tough and adaptable but also has many applications. Natural sunlight and ozone both harm it, making it brittle over time, but some rubbers, like EPDM, are made for toughness and can withstand a variety of harsh situations. EPDM rubber composites reinforced with three different kinds of reinforcement nanoparticles are employed in the manufacturing of rubber diaphragms. The combined use of analytical, numerical, and statistical methods provides a comprehensive framework for predicting and validating the mechanical performance of EPDM nanocomposites. Based on this, the estimated mechanical properties of Graphene nanoparticles yielded higher values than those of carbon nanotubes and Silica nanoparticles, respectively. Moreover, both CNT and Graphene showed the maximum tensile modulus, impact strength, and fatigue life, while the tensile modulus at 5 wt% increased from 3.5 MPa to above 7 MPa. The coefficient of determination (R²) values remain close to unity, providing strong evidence of a positive correlation between experimental measurements and model predictions. This confirms that the model successfully captures the underlying material behavior and the influence of nanofiller content.

References

Akrami, H., & Park, C. B. (2024). Advanced polycarbonate foam: Enhancing foamability and mechanical properties with toughened polycarbonate using nanofibrillation method and crosslinked rubbery EPDM networks. Journal of Manufacturing Processes, 127, 340-348. https://doi.org/10.1016/j.jmapro.2024.07.105

Amani, A. M., Tayebi, L., Rezaeeparto, K., Parham, S., Azizli, M. J., Vafa, E., Kamyab, H., Rajendran, S., & Simancas-Racines, D. (2025). Enhancement of mechanical properties in ethylene propylene diene monomer/natural rubber nanocomposites through Ti3C2TX reinforcement and EPDM-g-MAH compatibilization. Diamond and Related Materials, 157, 112535. https://doi.org/10.1016/j.diamond.2025.112535

Azizli, M. J., Barghamadi, M., Rezaeeparto, K., Mokhtary, M., & Parham, S. (2020). Compatibility, mechanical and rheological properties of hybrid rubber NR/EPDM-g-MA/EPDM/graphene oxide nanocomposites: theoretical and experimental analyses. Composites Communications, 22, 100442. https://doi.org/10.1016/j.coco.2020.100442

Bingöl, M. C., Yetgin, S. H., Köprü, İ., & Ulusal, F. (2025). Investigation of the properties of mesoporous-SiO2 filled EPDM (ethylene propylene diene monomer) rubber. Inorganic Chemistry Communications, 174, 114061. https://doi.org/10.1016/j.inoche.2025.114061

Burgoa, A., Arrillaga, A., & Schreier-Alt, T. (2024). Effect of multiple recycling on thermo-mechanical and rheological behaviour of PP/EPDM thermoplastic vulcanizates. Journal of Polymers and the Environment, 32(2), 947-961. https://doi.org/10.1007/s10924-023-03042-2

Colom, X., Marín, M., Saeb, M. R., Formela, K., & Cañavate, J. (2024). Recycling devulcanized EPDM to improve engineering properties of SBR rubber compounds. Resources, Conservation & Recycling Advances, 23, 200227. https://doi.org/10.1016/j.rcradv.2024.200227

Cui, Z., Liu, W., Tan, L., Sun, G., & Hu, X. (2024). Evidence for non-Arrhenius behavior of EPDM rubber by combining Arrhenius and time–temperature superposition (TTS) extrapolations. RSC advances, 14(8), 5216-5221. https://doi.org/10.1039/d3ra07159f

de Souza, E. L., de Sousa Zanzi, M., de Paiva, K. V., Oliveira, J. L. G., de Oliveira Barra, G. M., & Dutra, G. B. (2025). Experimental and numerical analyses of thermo-oxidative aging in NBR and EPDM rubber with different lengths. Polymer, 334, 128694. https://doi.org/10.1016/j.polymer.2025.128694

Du, X., Li, F., Qin, F., Chu, J., Dang, W., Hu, X., Zhang, X., Zhao, K., & Tang, Y. (2025). A review of ceramizable EPDM composites: Current status and future perspectives. Polymer Degradation and Stability, 238, 111345. https://doi.org/10.1016/j.polymdegradstab.2025.111345

Eyssa, H., Maziad, N. A., Kansouh, W., & Ramadan, W. (2024). Neutron attenuation performance of EPDM rubber with BN Nanoparticles/B2O3 composite and studying physical, thermal and mechanical properties. Nuclear Engineering and Technology, 56(11), 4563-4577. https://doi.org/10.1016/j.net.2024.06.019

Fang, W., Cai, Y., Zhu, J., Ma, Y., Gou, H., Wang, H., & Fan, H. (2025). Preparation of polysiloxane-functionalized polyolefin with unsaturated groups for improving the compatibility of EPDM/silicone rubber blends. European Polymer Journal, 234, 114029. https://doi.org/10.1016/j.eurpolymj.2025.114029

Foltuț, D., Uțu, I.-D., & Șerban, V.-A. (2025). Tribological Performance of EPDM and TPV Elastomers Against Glass Fiber-Reinforced Polyamide 66 Composites. Materials, 18(11), 2515. https://doi.org/10.3390/ma18112515

Gong, C., Xie, C., Zhu, H., Ding, W., Song, J., & Ge, Y. (2024). Time-varying compressive properties and constitutive model of EPDM rubber materials for tunnel gasketed joint. Construction and Building Materials, 433, 136734. https://doi.org/10.1016/j.conbuildmat.2024.136734

Gupta, P., Chattopadhyay, S., & Das, N. C. (2025). Short fiber reinforced elastomeric composites with enhanced mechanical and tribological properties for potential application in V-belts. Frontiers in Mechanical Engineering, 11, 1629780. https://doi.org/10.3389/fmech.2025.1629780

Hayeemasae, N., & Ismail, H. (2023). Comparative Studies of Natural Rubber/Virgin Ethylene Propylene Diene Rubber and Natural Rubber/Recycled Ethylene Propylene Diene Rubber and Natural Rubber/Blends. In Recycled Polymer Blends and Composites: Processing, Properties, and Applications (pp. 179-207). Springer. https://doi.org/10.1007/978-3-031-37046-5_9

Hou, N., Guo, Q., Zairi, F., Tian, L., & Ding, N. (2025). Predicting viscoelastic behavior and crack propagation in EPDM rubber under long-term thermal aging. Engineering Fracture Mechanics, 315, 110782. https://doi.org/10.1016/j.engfracmech.2024.110782

Khaleel, H. H., & Al-Hadrayi, Z. M. (2025). Free Vibration Analysis of Rotating Functionally Graded Material Beams on Elastic Foundations Using the Homotopy Perturbation Method. Mathematical Modelling of Engineering Problems, 12(8). https://doi.org/10.18280/mmep.120818

Khozemy, E. E., Nasef, S. M., & Radi, H. (2024). A comparative study of the mechanical and thermal properties of EPDM rubber/cement kiln dust composite cured by ionizing radiation. International Journal of Polymer Analysis and Characterization, 29(5), 282-299. https://doi.org/10.1080/1023666X.2024.2360855

Kiran, L. P., Venkataramiah, P., & Rani, S. U. (2023). Experimental study of vibration attenuation at rail joints by using Ethylene propylene Diene Monomer (EPDM) rubber. Materials Today: Proceedings, 80, 1317-1326. https://doi.org/10.1016/j.matpr.2023.01.063

Lee, S.-H., Yang, S.-W., Park, E.-S., Hwang, J.-Y., & Lee, D.-S. (2019). High-performance adhesives based on maleic anhydride-g-EPDM rubbers and polybutene for laminating cast polypropylene film and aluminum foil. Coatings, 9(1), 61. https://doi.org/10.3390/coatings9010061

Li, X., & Gong, Z. (2024). Investigation of long-term waterproof performance and hardness change of EPDM rubber gasket used for shield tunnels. Journal of Materials in Civil Engineering, 36(2), 04023577. https://doi.org/10.1061/JMCEE7.MTENG-16744

Ling, Y., Liu, J., Xiao, B., Jin, H., Zhao, L., Bai, Y., Zhang, X., Liang, M., Chen, Y., & Zou, H. (2025). High mechanical interlocking and hydrogen bonding based carboxymethyl cellulose/SiO2 composite structures for interfacial bonding of reinforced polyimide fiber/EPDM composites. Composites Part B: Engineering, 304, 112652. https://doi.org/10.1016/j.compositesb.2025.112652

Luo, Y., Wang, X., Ding, J., & Chen, Y. (2025). Large‐scale recycling of waste cross‐linked ethylene propylene diene monomer enabled by devulcanization‐grafting strategy. Polymer Engineering & Science, 65(6), 3163-3177. https://doi.org/10.1002/pen.27206

Marin-Genesca, M., Garcia-Amoros, J., Mudarra, M., Massagués Vidal, L., Canavate, J., & Colom, X. (2023). Insights into the structural and dielectric behavior of composites produced from EPDM waste processed through a devulcanization method and SBR. ACS omega, 8(14), 12830-12841. https://doi.org/10.1021/acsomega.2c08115

Moustafa, H., Lawandy, S. N., Rabee, M., & Zahran, M. A. (2020). Effect of green modification of nanoclay on the adhesion behavior of EPDM rubber to polyester fabric. International Journal of Adhesion and Adhesives, 100, 102617. https://doi.org/10.1016/j.ijadhadh.2020.102617

Mukhopadhyay, A., & Roy, D. (2023). Study on abrasive wear pattern of ethylene propylene dyne monomer (EPDM) rubber compound. Materials Today: Proceedings, 78, 476-480. https://doi.org/10.1016/j.matpr.2022.10.297

Ndour, I., Mougne, Q., Falzon, M. F., & Richaud, E. (2025). Thermal ageing of PP-EPDM thermoplastic vulcanizate: Multiscale study and kinetic modeling. Polymer Degradation and Stability, 240, 111478. https://doi.org/10.1016/j.polymdegradstab.2025.111478

Prut, E. V., Solomatin, D. V., & Kuznetsova, O. P. (2017). Rheological behaviors of blends based on polypropylene and EPDM rubber powder. Mendeleev Communications, 27(3), 318-320. https://doi.org/10.1016/j.mencom.2017.05.035

Sharma, S. K., Miladinović, S., Sharma, L. K., Gajević, S., Sharma, Y., Sharma, M., Čukić, S., & Stojanović, B. (2026). Graphene/CNT Nanocomposites: Processing, Properties, and Applications. Nanomaterials, 16(2), 100. https://doi.org/10.3390/nano16020100

Simet, C., Mougin, K., Moreau, M., Perche, M., Vaulot, C., Ponche, A., & Bally–Le Gall, F. (2023). Investigation of ethylene-propylene-diene monomer (EPDM) ageing behaviour in PMDIs environment by surface NMR. Polymer Testing, 127, 108171. https://doi.org/10.1016/j.polymertesting.2023.108171

Spanheimer, V., Šimić, D., Katrakova‐Krüger, D., & Giese, U. (2025). Thermo‐Oxidative Aging and Performance Comparison of Recovered, Sustainable, and Virgin Carbon Black in Ethylene Propylene Diene Monomer‐Based Elastomers. Macromolecular Materials and Engineering, 310(8), 2500034. https://doi.org/10.1002/mame.202500034

Spencer, M. P., Zwoster, A., Bisel, T. T., Murphy, M. K., & Fifield, L. S. (2020). Sequential versus Simultaneous Aging of EPDM Nuclear Cable Insulation Subjected to Elevated Temperature and Gamma Radiation. In 2020 IEEE Conference on Electrical Insulation and Dielectric Phenomena (CEIDP) (pp. 470-474). IEEE. https://doi.org/10.1109/CEIDP49254.2020.9437502

Sumbodo, W., Pambudi, R., & Setiadi, R. (2025). Design and Analysis of Pick and Place Robot Gripper in the Fertilizer Industry. Reports in Mechanical Engineering, 6(2), 53-64. https://doi.org/10.31181/rme511

Triganza, T., Refalo, P., Rochman, A., & Brancaleone, R. P. (2025). Process Parameter Optimization for Sustainable Manufacturing of Elastomeric Components Used in Water Treatment Systems. Procedia CIRP, 135, 991-996. https://doi.org/10.1016/j.procir.2025.01.092

Vishvanathperumal, S., & Anand, G. (2021). Effect of nanosilica and crosslinking system on the mechanical properties and swelling resistance of EPDM/SBR nanocomposites with and without TESPT. Silicon, 13(10), 3473-3497. https://doi.org/10.1007/s12633-020-00792-9

Wang, Q., Yao, M., Quan, Y., & Zhuang, D. (2024). Simultaneously achieving excellent heat aging resistance and grip performance in carbon black/glass flake/EPDM rubber composite for overhead line spacers. Materials Today Communications, 39, 108878. https://doi.org/10.1016/j.mtcomm.2024.108878

Wang, Y., Li, J., Wan, L., Wang, L., & Li, K. (2023). A lightweight rubber foaming insulation reinforced by carbon nanotubes and carbon fibers for solid rocket motors. Acta Astronautica, 208, 270-280. https://doi.org/10.1016/j.actaastro.2023.04.019

Wang, Z., Wang, J., Wu, H.-N., Zhang, R., Zhang, G.-y., Zhang, F., & Mariani, S. (2025). Investigation of the microstructure, mechanical properties and thermal degradation kinetics of EPDM under thermo-stress conditions used for joint sealing of floating prefabricated concrete platform of offshore wind power. Construction and Building Materials, 485, 141897. https://doi.org/10.1016/j.conbuildmat.2025.141897

Xu, D.-H., Zhou, Y., He, W.-D., Wu, H.-M., & Yu, J. (2019). Influence of rubber ratio and crosslinking agent on mechanical properties, crystallization and rheological behaviors of EPDM/PP thermoplastic elastomer. International Polymer Processing, 34(4), 457-466. https://doi.org/10.3139/217.3817

Xu, J., Cheng, Z., Ke, Y., Yang, C., Wang, B., & Hu, Y. (2025). Combined application of synergists from bittern and bio-based multifunctional modifiers to EPDM rubber composites: processing, fire safety, mechanical and anti-aging properties. Chemical Engineering Journal, 515, 163377. https://doi.org/10.1016/j.cej.2025.163377

Xu, M., Chen, L., & Zong, C. (2025). The effect of rubber and plastic mass ratio on the compatibilized ethylene propylene diene monomer/polypropylene TPV with shape memory behavior. Journal of Applied Polymer Science, 142(2), e56330. https://doi.org/10.1002/app.56330

Yu, F., Long, C., Feng, S., Dong, Z., Liu, X., Li, Y., & Chen, Z.-R. (2025). In-situ grafted ethylene propylene diene monomer (EPDM) rubber multiblock copolymers as compatibilizers for polyethylene (PE) and isotactic polypropylene (iPP) blends. Polymer, 317, 127959. https://doi.org/10.1016/j.polymer.2024.127959

Zhang, C., Wu, J., Teng, F., Su, B., Wang, Y., & Ao, H. (2021). Theoretical and experimental characterization for macro-micro friction behaviors of EPDM rubber. Polymer Testing, 99, 107213. https://doi.org/10.1016/j.polymertesting.2021.107213

Downloads

Published

2026-08-13

How to Cite

Mechanical Performance Enhancement of EPDM Rubber Nanocomposites Reinforced with Graphene, Carbon Nanotubes, and Silica for Industrial Diaphragm Applications. (2026). Reports in Mechanical Engineering, 7(2), 44-66. https://doi.org/10.5281/zenodo.21910721